Some things you want to have bubbles, some you don’t.
In beermaking, yeast consumes the sugars in the wort and convert them into CO2 gas bubbles- carbonation.
In steel making the main reaction is the combination of Carbon in the melt with Oxygen to form a gas. At the high temperatures involved, this gas is very soluble in the molten bath.
If the Oxygen that is available for this chemical reaction isn’t completely removed before the steel is cast the gases will continue to be forced out of the melt during solidification, resulting in porosity in the steel.
In order to control the evolution of gas, chemicals called deoxidizers are added to the steel. These chemicals, Silicon or Aluminum, Vanadium, Columbium, Niobium scavenge the available oxygen in the molten steel, react chemically to form solid oxide particles dispersed throughout the steel, rather than bubbles of Carbon Dioxide.
The amount and type of deoxidizer added determines the type of steel. If sufficent deoxidizers are added, no gas is evolved from the solidifying steel, and the steel is said to be “killed.” The ingot drawing labelled number 1 shows a fully killed (deoxidized) steel showing only a shrinkage cavity, and no bubbles or porosity. ( This shrinkage cavity would be cropped off in normal rolling practice.)
Killed steel has more uniform chemical composition and properties than rimmed, semi-killed, or non-killed steels, and generally less segregation. The uniformity of killed steel and and its freedom from porosity makes these steels more suitable for critical components and for applications involving heat treatment.
Killed steels generally contain 0.15-.35 weight percent Silicon as a deoxidizer, and may contain some of the other elements as mentioned above. These other elements may be used as deoxidizers or as grain refiners.
Steel grades with a Carbon maximum of 0.30 weight % and above, and all alloy steels are typically provided as “killed steels.”
Free machining steels such as 12L14, 1215, and some 11XX series steels are not “killed” with Silicon, Aluminum, etc., due to their deleterious effects on tool life and machinability. The high amounts of Manganese in these steels form Manganese Sulfides to promote machinability, and also the Manganese scavenges excess Oxygen, preventing evolution of CO2.
Killed steel- for critical parts. Non-killed beer for critical after work down time.
Ingot scan from a handout in my files originally after Making Shaping and Treating of Steel.
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